CHARACTERIZATION AND POTENTIAL APPLICATION OF DEXTRAN-BASED BIOPOLYMER POWDER OBTAINED FROM HYDRANGEA MACROPHYLLA LIQUID ANTHOCYANINS EXTRACT BY ULTRASONIC EXTRACTION
Keywords:
(Bio)polymers, Dextran, Hydrangea macrophylla, Latent Fingerprints, ForensicsAbstract
Biopolymers have numerous advantages, such are biodegradable, non-toxic, non-inflammatory and biocompatible properties, and, therefore, have a potential for various applications. In this paper dextran-based biopolymer powder, obtained from Hydrangea macrophylla liquid anthocyanins extract by ultrasonic extraction and simple precipitating method, was synthetized and characterized in order to determine its properties and potential application. ATR FT-IR analyses showed interactions between components of the system. Optical microscopy suggested that prepared biopowder formulation was small and somewhat uniform in size, and also showed its easy binding to the fingerprint residues. Additionally, prepared biopolymer powder was used to visualize latent fingerprints left on different non-porous and semi-porous surfaces, i.e. flat wood, glass, plastic and rubber. The results demonstrated the potential of obtained dextran-based biopowder to complement routinely applied systems in developing latent fingerprints.
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2. Araya-Hermosilla, E., Muñoz, D., Orellana, S., Yáñez, A., & Olea, A. F. (2014). Immobilization of rhodamine 6G in calcium alginate microcapsules based on aromatic–aromatic interactions with poly(sodium 4-styrenesulfonate). Reactive and Functional Polymers, 81, 14-21.
3. Bumbrah, G. S., Sharma, R., & Jasuja, O. (2016). Emerging latent fingerprint technologies: a review. Research and Reports in Forensic Medical Science, 6, 39-50.
4. Cakić, M., Nikolić, G., Ilić, L., & Stanković, S. (2005). Synthesis and FTIR Characterization of Some Dextran Sulphates. CI&CEQ, 1(2), 1-5.
5. Carp, O., Patron, L., Culita, D. C., Budrugeac, P., Feder, M., & Diamandescu, L. (2010). Thermal analysis of two types of dextran-coated magnetite. Journal of Thermal Analysis and Calorimetry, 101(1), 181–187.
6. Champod, C., Lennard, C. J., Margot, P., & Stoilovic, M. (2004). Fingerprints and Other Ridge Skin Impressions (2nd ed.). Boca Raton, Florida: CRC Press, Taylor & Francis.
7. Chandrasekhar, J., Madhusudhan, M. C., & Raghavarao, K. S. (2012). Extraction of anthocyanins from red cabbage and purification using adsorption. Food and Bioproducts Processing, 90(4), 615–623.
8. Chiu, H.-C., Hsiue, T., & Chen, W.-Y. (2004). FTIR-ATR measurements of the ionization extent of acrylic acid within copolymerized methacrylated dextran/acrylic acid networks and its relation with pH/salt concentration-induced equilibrium swelling. Polymer, 45(5), 1627-1636.
9. Dilag, J., Kobus, H., & Ellis, A. V. (2009). Cadmium sulfide quantum dot/chitosan nanocomposites for latent fingermark detection. Forensic Science International, 187, 97-102.
10. Färber, D., Seul, A., Weisser, H., & Bohnert, M. (2010). Recovery of latent fingerprints and DNA on human skin. Journal of Forensic Sciences, 55(6), 1457-1461.
11. Guerrero, P., Kerry, J. P., & de la Caba, K. (2014). FTIR characterization of protein–polysaccharide interactions in extruded blends. Carbohydrate Polymers, 111, 598-605.
12. International Fingerprint Research Group (IFRG). (2014). Guidelines for the Assessment of Fingermark Detection Techniques. Accessed on July 10, 2021. https://ifrg.unil.ch/wp-content/uploads/2014/06/IFRG-Research-Guidelines-v1-Jan-2014.pdf.
13. Lee, J., Pyo, M., Lee, S., Kim, J., Ra, M., Kim, W.-Y., Park, B. J., Lee, C. W., & Kim, J.-M. (2014). Hydrochromic conjugated polymers for human sweat pore mapping. Nature Communications, 5, 10.
14. Lennard, C. (2007). Fingerprint detection: current capabilities. Australian Journal of Forensic Sciences, 39(2), 55-71.
15. Mehta, R. V., Rucha, D., Bhatt, P., & Upadhyay, R. V. (2006). Synthesis and characterization of certain nanomagnetic particles coated with citrate and dextran molecules. Indian Journal of Pure and Applied Physics, 44(7), 537-542.
16. Milašinović, N. (2016). Polymers in Criminalistics: Latent Fingerprint Detection and Enhancement – From Idea to Practical Application. NBP – Journal of Criminalistics and Law, 133-148.
17. Mitić, Ž., Cakić, M., & Nikolić, G. (2010). Fourier-Transform IR spectroscopic investigations of Cobalt(II)–dextran complexes by using D2O isotopic exchange. Spectroscopy, 24, 269–275.
18. Mitrović, V. (1998). Kriminalistička identifikacija: teorija i praksa. Belgrade.
19. Mozayani, A., & Noziglia, C. (2006). The Forensic Laboratory Handbook Procedures and Practice. Totowa, New Jersey: Humana press.
20. Nikolić, G. S., Cakić, M., Mitić, Ž., & Ilić, L. (2008). Deconvoluted Fourier-transform LNT-IR study of coordination copper(II) ion compounds with dextran derivatives. Russian Journal of Coordination Chemistry, 34(5), 322–328.
21. Vučković, N., Dimitrijević, S., & Milašinović, N. (2020). Visualization of Latent Fingerprints Using Dextran-based Micropowders Obtained From Anthocyanin Solution. Turkish Journal of Forensic Sciences and Crime Studies, 2(2), 3–53.
22. Vučković, N., Glođović, N., Radovanović, Ž., Janaćković, Đ., & Milašinović, N. (2020). A novel chitosan/tripolyphosphate/L-lysine conjugates for latent fingerprints detection and enhancement. Journal of Forensic Sciences, 66(1), 149–160. doi:10.1111/1556-4029.14569.
23. Wang, R., Dijkstra, P. J., & Karperien, M. (2016). Dextran. In N. M. Neves, & R. I. Reis (Eds.), Biomaterials from Nature for Advanced Devices and Therapies (pp. 307-316). New Jersey: John Wiley & Sons, Inc.
24. Wanga, Y. F., Yang, R. Q., Wanga, Y. F., Shi, Z. X., & Liu, J. J. (2009). Application of CdSe nanoparticle suspension for developing latent fingermarks on the sticky side of adhesives. Forensic Science International, 185, 96-99.
25. Wasiak, I., Kulikowska, A., Janczewska, M., Michalak, M., Cymerman, I. A., Nagalski, A., Kallinger, P., Szymanski, W. W., & Ciach, T. (2016). Dextran Nanoparticle Synthesis and Properties. PLOS ONE, 11(1), 1-17.
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Published
2021-11-26
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Section
Innovative Techniques and Equipment in Forensic Engineering
